MPG

The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogenated N-compounds(inorg) / NCl3 / ClarkClyne(1969)_300K_230nm

DATAFILE: NCl3_ClarkClyne(1969)_300K_230nm.txt
NAME: nitrogen trichloride
FORMULA: NCl3
AUTHOR(YEAR): ClarkClyne(1969)
T: 300K
λ: 230nm
BIBLIOGRAPHY: T.C. Clark and M.A.A. Clyne, "Kinetic mechanisms in nitrogen-chlorine radical systems: Part 1.-The formation and detection of the NCl2 and N3 free radicals using time-resolved absorption spectrophotometry", Trans. Faraday Soc. 65, 2994-3004 (1969); DOI: 10.1039/TF9696502994
COMMENTS: The extinction coefficient 1190 ± 12 L mol-1 cm-1 was determined using the decomposition stoichiometry, and also the stoichiometry of the O+ NCl3 reaction investigated by

C.D. Clark and M.A.A. Clyne, Kinetic mechanisms in nitrogen + chlorine radical systems: Part 2.- Kinetics of elementary reactions of nitrogen trichloride and of the dichloramino free radical, Trans. Faraday Soc., 66, 372-385, 1970; DOI: 10.1039/TF9706600372

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