When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | NCl3_ClarkClyne(1969)_300K_230nm.txt |
NAME: | nitrogen trichloride |
FORMULA: | NCl3 |
AUTHOR(YEAR): | ClarkClyne(1969) |
T: | 300K |
λ: | 230nm |
BIBLIOGRAPHY: |
T.C. Clark and M.A.A. Clyne, "Kinetic mechanisms in nitrogen-chlorine radical systems: Part 1.-The formation and detection of the NCl2 and N3 free radicals using time-resolved absorption spectrophotometry",
Trans. Faraday Soc. 65, 2994-3004 (1969);
DOI: 10.1039/TF9696502994
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COMMENTS: | The extinction coefficient 1190 ± 12 L mol-1 cm-1 was determined using the decomposition stoichiometry, and also the stoichiometry of the O+ NCl3
reaction investigated by
C.D. Clark and M.A.A. Clyne, Kinetic mechanisms in nitrogen + chlorine radical systems: Part 2.- Kinetics of elementary reactions of nitrogen trichloride and of the dichloramino free radical, Trans. Faraday Soc., 66, 372-385, 1970; DOI: 10.1039/TF9706600372 |
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