MPG

The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

This page is obsolete, the new page is here:

https://www.uv-vis-spectral-atlas-mainz.org

Please update your bookmarks!

(This page may still be available for a while, but it won't be updated anymore)

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Home

Cross Sections

Quantum Yields

Errata

Contact, Impressum, Acknowledgements


When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Iodoalkanes(C,H,F,Cl,Br,I) / CH2BrI / JPL-2010(2011)_298K_215-390nm(rec)

DATAFILE: CH2BrI_JPL-2010(2011)_298K_215-390nm(rec).txt
NAME: bromoiodomethane
FORMULA: CH2BrI
AUTHOR(YEAR): JPL-2010(2011)
T: 298K
λ: 215-390nm(rec)
BIBLIOGRAPHY: S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17", JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
COMMENTS: JPL-2010 recommendation, adopting the earlier recommendations of

S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, R.E. Huie, V.L. Orkin, G.K. Moortgat, A.R. Ravishankara, C.E. Kolb, M.J. Molina, and B.J. Finlayson-Pitts, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 14“, JPL Publication 02-25, Jet Propulsion Laboratory, Pasadena, 2002; http://jpldataeval.jpl.nasa.gov/, and

S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/:

215-390 nm,

absorption cross sections of

J.C. Mössinger, D.E. Shallcross, and R.A. Cox, "UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2, and CH2BrI," J. Chem. Soc. Faraday Trans. 94, 1391-1396 (1998); DOI: 10.1039/A709160E

Temperature coefficients B:

273-348 K,

J.C. Mössinger, D.E. Shallcross, and R.A. Cox, "UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2, and CH2BrI," J. Chem. Soc. Faraday Trans. 94, 1391-1396 (1998); DOI: 10.1039/A709160E,

ln σ(λ, T) = ln σ(λ, 298 K) + B × (T - 298) with

-------------------
λ    103 B
(nm)  (K-1)
-------------------
215 -2.16
220 -0.12
225  1.34
230  2.06
235  2.05
240  1.01
245  0.00
250 -0.58
255 -1.16
260 -1.29
265 -1.45
270 -1.73
275 -1.22
280 -0.94*)
285 -0.53
290  0.10
295  0.63
300  1.03
305  1.13
310  1.41
315  1.52
320  1.71
325  2.36
330  2.99
335  3.89
340  4.79
345  5.74
350  6.73
355  9.47
360 11.50
365 11.60
370 14.30
375 17.40

*) B(280 nm) erroneously +0.00094 in Table 1; corrected to -0.00094, after personal communication with J. Mössinger (March 2001)

Search cross sections

Species search:

Identifier search:

Reference search:

Full text search:

Recent additions:
since ago