When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH2ICl_IUPAC(2008)_298K_205-390nm(rec).txt |
NAME: | chloroiodomethane |
FORMULA: | CH2ICl |
AUTHOR(YEAR): | IUPAC(2008) |
T: | 298K |
λ: | 205-390nm(rec) |
BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species",
Atmos. Chem. Phys. 8, 4141-4496 (2008);
DOI: 10.5194/acp-8-4141-2008
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COMMENTS: | IUPAC(2008) recommendation: Mean of the data of O.V. Rattigan, D.E. Shallcross, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis rates of CF3I, CH3I, C2H5I and CH2ICl," J. Chem. Soc. Faraday Trans. 93, 2839-2846 (1997); DOI: 10.1039/A701529A, and C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, and P.J. Crutzen, "Temperature dependence of UV absorption cross sections and atmospheric implications of several alkyl iodides," J. Geophys. Res. 102(D11), 12819-12829 (1997); DOI: 10.1029/97JD00530 The temperature dependence ln σ(T) = ln σ(298K) + B × (T - 298) and the temperature coefficients B (243-333 K): ------------------
λ 103 B
(nm) (K-1)
-----------------
235 0.24
240 0.12
245 -0.02
250 -0.11
255 -0.28
260 -0.44
265 -0.55
270 -0.59
275 -0.47
280 -0.18
285 0.32
290 0.99
295 1.73
300 2.56
305 3.08
310 3.50
315 3.56
320 3.46
325 3.44
330 3.72
335 4.09
340 4.87
345 5.69
350 6.88
355 8.16
360 9.01
365 11.06
370 11.47
375 12.77
380 15.14
385 19.12
390 20.48
are adopted from the work of Rattigan et al. (1997) |
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