MPG

The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

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1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Hypohalides+oxy acids of halogens / HOCl / Barnes(1998)_298K_200-550nm(2nm)

DATAFILE: HOCl_Barnes(1998)_298K_200-550nm(2nm).txt
NAME: hypochlorous acid
FORMULA: HOCl
AUTHOR(YEAR): Barnes(1998)
T: 298K
λ: 200-550nm(2nm)
BIBLIOGRAPHY: R.J. Barnes, A. Sinha, and H.A. Michelsen, "Assessing the contribution of the lowest triplet state to the near-UV absorption spectrum of HOCl", J. Phys. Chem. A 102, 8855-8859 (1998); DOI: 10.1021/jp9835869
COMMENTS: The near-UV absorption spectrum of HOCl is examined using laser induced fluorescence to monitor OH fragments resulting from photodissociation; continuously tunable laser radiation in the region 380-550 nm with bandwidths of 0.12 to 0.3 cm-1 was used

Absorption cross sections at 2-nm intervals were calculated by using a fit over the own data and those of

J.B. Burkholder, "Ultraviolet absorption spectrum of HOCl", J. Geophys. Res. 98, 2963-2974 (1993); DOI: 10.1029/92JD02522

and have been obtained by personal communication to Max-Planck-Institut für Chemie, Mainz, Germany

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