MPG

The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

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1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Organics (N-compounds) / Nitrates / n-C3H7ONO2 / ZhuKellis(1997)_298K_265-340nm

DATAFILE: n-C3H7ONO2_ZhuKellis(1997)_298K_265-340nm.txt
NAME: 1-propyl nitrate
FORMULA: n-C3H7ONO2
AUTHOR(YEAR): ZhuKellis(1997)
T: 298K
λ: 265-340nm
BIBLIOGRAPHY: L. Zhu and D. Kellis, "Temperature dependence of the UV absorption cross sections and photodissociation products of C3 - C5 alkyl nitrates", Chem. Phys. Lett. 278, 41-48 (1997); DOI: 10.1016/S0009-2614(97)01011-7
COMMENTS: The temperature dependence of the absorption cross sections has been measured (cavity ring-down spectroscopy) at 238, 248, 258, 268, 278, 288, and 298K and parameterized to the empirical equation

σ(T, λ) = σ(298 K, λ) × exp[B × (T - 298)] with the temperature coefficients B:

--------------------
λ  103 B
(nm) (K-1)
--------------------
265  3.29
270  3.44
275  3.72
280  3.98
285  4.22
290  4.76
295  4.94
300  5.11
305  5.66
310  6.41
315  6.79
320  7.89
325  8.90
330  9.66
335 11.5
340 14.5

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