MPG

The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

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1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Organics (acids) / HC(O)OOH / Indulkar(2014)_298K_280-360nm

DATAFILE: HC(O)OOH_Indulkar(2014)_298K_280-360nm.txt
NAME: peroxyformic acid (PFA)
FORMULA: HC(O)OOH
AUTHOR(YEAR): Indulkar(2014)
T: 298K
λ: 280-360nm
BIBLIOGRAPHY: Y.N. Indulkar, M.K. Louie, and A. Sinha, "UV photochemistry of peroxyformic acid (HC(O)OOH): An experimental and computational study investigating 355 nm photolysis", J. Phys. Chem. A, 118, 5939-5949 (2014); DOI: 10.1021/jp5039688
COMMENTS: Interpolation using the Gaussian functional form

σ(λ) = σ0 exp -{[(107/λ) - a]2/2b2} with

σ0 = 4.6 x 10-20 fixed to the σ0 value of H2O2 and scaled down
a = 42500 ± 300 cm-1
b = 3770 ± 100 cm-1

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