MPG

The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Peroxy radicals / Alkylperoxy+F / CH2FO2 / Lightfoot(1992)_298K_210-300nm(rec)

DATAFILE: CH2FO2_Lightfoot(1992)_298K_210-300nm(rec).txt
NAME: fluoromethylperoxy radical
FORMULA: CH2FO2
AUTHOR(YEAR): Lightfoot(1992)
T: 298K
λ: 210-300nm(rec)
BIBLIOGRAPHY: P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry", Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I
COMMENTS: Recommendation based on a smooth fit to the data of

P. Dagaut, T.J. Wallington, and M.J. Kurylo, "The UV absorption spectra and kinetics of the self reactions of CH2ClO2 and CH2FO2 radicals in the gas phase," Int. J. Chem. Kinet. 20, 815-826 (1988), and

T.J. Wallington, J.C. Ball, O.J. Nielsen, and E. Bartkiewicz, "Spectroscopic, kinetic, and mechanistic study of CH2FO2 radicals in the gas phase at 298 K," J. Phys. Chem. 96, 1241-1246 (1992)

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