The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

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1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Cross Sections

Quantum Yields


Contact, Impressum, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+F / CH2FO2 / Lightfoot(1992)_298K_210-300nm(rec)

DATAFILE: CH2FO2_Lightfoot(1992)_298K_210-300nm(rec).txt
NAME: fluoromethylperoxy radical
AUTHOR(YEAR): Lightfoot(1992)
T: 298K
λ: 210-300nm(rec)
BIBLIOGRAPHY: P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry", Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I
COMMENTS: Recommendation based on a smooth fit to the data of

P. Dagaut, T.J. Wallington, and M.J. Kurylo, "The UV absorption spectra and kinetics of the self reactions of CH2ClO2 and CH2FO2 radicals in the gas phase," Int. J. Chem. Kinet. 20, 815-826 (1988), and

T.J. Wallington, J.C. Ball, O.J. Nielsen, and E. Bartkiewicz, "Spectroscopic, kinetic, and mechanistic study of CH2FO2 radicals in the gas phase at 298 K," J. Phys. Chem. 96, 1241-1246 (1992)

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