MPG

The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

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1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Silicon compounds / (CH3)2Si=CH2 / Brix(1989)_298K_212.5-297.5nm(smoo)

DATAFILE: (CH3)2Si=CH2_Brix(1989)_298K_212.5-297.5nm(smoo).txt
NAME: dimethylsilaethene
FORMULA: (CH3)2Si=CH2
AUTHOR(YEAR): Brix(1989)
T: 298K
λ: 212.5-297.5nm(smoo)
BIBLIOGRAPHY: T. Brix, N.L. Arthur, and P. Potzinger, "Stationary and pulsed photolysis and pyrolysis of 1,1-dimethylsilacyclobutane", J. Phys. Chem. 93, 8193-8197 (1989); DOI: 10.1021/j100362a011
COMMENTS: Laser pulsed photolysis at 193 nm of 1,1-dimethylsilacyclobutane yields dimethylsilaethene and C2H4

The absorption spectrum of dimethylsilaethene was measured using a D2 lamp as a light source, a monochromator and a photomultiplier

The smooth fit to the measured data plotted in Fig. 2 has been digitized

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